|
|
S-adenosyl-L-methionine + O-methyl-4-O-[2-O-methyl-alpha-L-fucopyranosyl-(1rarr3)-alpha-L-rhamnopyranosyl-(1rarr3)-2-O-methyl-alpha-L-rhamnopyranosyl]-hydroxybenzoate <=> O-methyl-4-O-[2,4-di-O-methyl-alpha-L-fucopyranosyl-(1rarr3)-alpha-L-rhamnopyranosyl-(1rarr3)-2-O-methyl-alpha-L-rhamnopyranosyl]-hydroxybenzoate + S-adenosyl-L-homocysteine + H+
|
2.1.1.M15
|
–
|
| |
MetaCyc:
RXN-17284
|
|
|
|
dTDP-L-rhamnose + p-HBAD-I <=> O-methyl-4-O-[alpha-L-rhamnopyranosyl-(1rarr3)-2-O-methyl-alpha-L-rhamnopyranosyl]-hydroxybenzoate + dTDP + H+
|
2.4.1.M4
|
–
|
| |
MetaCyc:
RXN-17293
|
|
|
|
GDP-L-fucose + O-methyl-4-O-[alpha-L-rhamnopyranosyl-(1rarr3)-2-O-methyl-alpha-L-rhamnopyranosyl]-hydroxybenzoate <=> O-methyl-4-O-[alpha-L-fucopyranosyl-(1rarr3)-alpha-L-rhamnopyranosyl-(1rarr3)-2-O-methyl-alpha-L-rhamnopyranosyl]-hydroxybenzoate + GDP + H+
|
2.4.1.M5
|
–
|
| |
MetaCyc:
RXN-17286
|
|
|
|
S-adenosyl-L-methionine + O-methyl-4-O-[2,4-di-O-methyl-alpha-L-fucopyranosyl-(1rarr3)-alpha-L-rhamnopyranosyl-(1rarr3)-2-O-methyl-alpha-L-rhamnopyranosyl]-hydroxybenzoate <=> p-HBAD-II + S-adenosyl-L-homocysteine + H+
|
2.1.1.M16
|
–
|
| |
MetaCyc:
RXN-17283
|
|
|
|
S-adenosyl-L-methionine + O-methyl-4-O-[alpha-L-fucopyranosyl-(1rarr3)-alpha-L-rhamnopyranosyl-(1rarr3)-2-O-methyl-alpha-L-rhamnopyranosyl]-hydroxybenzoate <=> O-methyl-4-O-[2-O-methyl-alpha-L-fucopyranosyl-(1rarr3)-alpha-L-rhamnopyranosyl-(1rarr3)-2-O-methyl-alpha-L-rhamnopyranosyl]-hydroxybenzoate + S-adenosyl-L-homocysteine + H+
|
2.1.1.M14
|
–
|
| |
MetaCyc:
RXN-17285
|
|
|
|
S-adenosyl-L-methionine + 4-O-(alpha-L-rhamnopyranosyl)-hydroxybenzoate_methyl_ester <=> p-HBAD-I + S-adenosyl-L-homocysteine + H+
|
2.1.1.M13
|
–
|
| |
MetaCyc:
RXN-17288
|
|
|
|
chorismate <=> 4-hydroxybenzoate + pyruvate
|
4.1.3.40
chorismate lyase
|
–
|
| |
BRENDA:
BR48792
KEGG:
R01302
MetaCyc:
CHORPYRLY-RXN
|
|
|
|
S-adenosyl-L-methionine + 4-hydroxybenzoate <=> S-adenosyl-L-homocysteine + methyl_4-hydroxybenzoate
|
2.1.1.274
salicylate 1-O-methyltransferase
2.1.1.M17
|
–
–
|
| |
BRENDA:
BS425005
MetaCyc:
RXN-17303
|
|
|
|
methyl_4-hydroxybenzoate + dTDP-L-rhamnose <=> 4-O-(alpha-L-rhamnopyranosyl)-hydroxybenzoate_methyl_ester + dTDP + H+
|
2.4.1.M3
|
–
|
| |
MetaCyc:
RXN-17292
|
|
